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Setting up IPv6 address for IRC usage works like this:
# /sbin/ifconfig
eth0 Link encap:Ethernet HWaddr 00:30:05:d4:b2:c8
inet addr:62.75.255.124 Bcast:0.0.0.0 Mask:255.255.255.255
inet6 addr: 2001:470:1f0b:86f::402/128 Scope:Global
UP BROADCAST RUNNING MULTICAST MTU:1500 Metric:1
RX packets:514978352 errors:0 dropped:0 overruns:0 frame:0
TX packets:539909937 errors:0 dropped:0 overruns:0 carrier:0
collisions:0 txqueuelen:1000
RX bytes:2710550256 (2.5 GiB) TX bytes:1741772379 (1.6 GiB)
Interrupt:9 Base address:0xe000
Look for the address in the inet6 section. Next, Set your IPv6 address inside irssi client
# irssi
/set hostname 2001:470:1f0b:86f::402
/connect -6 irc.ipv6.freenode.net